1.

An inorganic Lewis acid (X) fumes in moist air and intensity of fumes increases when a rod dipped in NH_(4)OH is brought near to it. An acidic solution of) on addition of NH_(4)Cl and NH_(4)OH.gives a precipitate which dissolves in NaOH solution. An acidic solution of (X) does not give precipitate with H_(2)S. Hence, the compound is

Answer»

`FeCl_(3)`
`AlCl_(3)`
`SnCl_(2)`
`ZnCl_(2)`

Solution :`(X) is `AlCl_(3)`
`AlCl_(3)underset(moisture)(+3H_(2)O)toAl(OH)_(2)darrunderset(fumes)(+3HCL)`
`AlCl_(3)+3NH_(4)OHtoAl(OH)_(3)darr+3NH_(4)Cl`
`AL(OH)_(3)+NaOHtoNaAlO_(2)+H_(2)O`
`AlCl_(3)+H_(2)S+H^(+)to"No ppt."`
HENCE,(B) is the CORRECT answer.


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