1.

An equimolar mixture of toluene and chlorobenzene is treated with a mixture of conc. H_(2)SO_(4) and conc. HNO_(3). Indicate the correct statement from the following:

Answer»

p-nitrotoluene is formed is EXCESS
Equimolar amount of p-nitrotoluene and p-chloronitro BENZENE are formed.
p-chloronitrobenzene is formed in excess
m-chloronitrobenzene is formed in excess.

Solution :
both toluene and chlorobenzene can be nitrated under the reaction condition. However, `-CH_(3)` GROUP is more reactive or ACTIVATING as compared to `-Cl` atom. This means that p-nitrotoluene is formed in excess


Discussion

No Comment Found