1.

An aqueoussolution containing 1 mol of HgI_(2) and 2 molof Nal is orange in colour .Onadditionod excessNaI , thesolutionbecomescolourless .Theorangecolour reappearsonsubsequent addition of NaOCl.

Answer»

Solution :`HgI_(2)` is having orange / scarletcolour it dissolvein sodiumiodidedue to theformation of a complex .
`HgI_(2) + 2Nal RARR Na_(2)HgI_(4)`
with `NaOCI` AGENT a PRECIPITATE of `HgI_(2)` is FORMED
`3Na_(2)HgI_(4) + 2NaOCI + 2H_(2)O rarr 3HgI_(2) + 2NaI_(3) + 4NaOH + 2NaCI`


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