1.

An alkyl halide with beta-hydrogen atoms when reacted with a base or a nucleophile has two competing routes: substitution (S_(N)1 and S_(N)2) and elimination. Which route will be taken up depends upon the nature of the alkyl halide, strength and size of the base/nucleophile and reaction conditions. thus, bulkier nucleophile prefers to act as a base and abstracts a proton rather than approaching a tetravalent carbon atom (steric reaction) and vice-versa. Q. Isopropyl bromide on heating with a concentrated solution of alcoholic (ethanolic) KOH predominantly gives

Answer»

Propene
Propan-2-ol
Propan-1-ol
Isopropyl ETHYL ether

Solution :`C_(2)H_(5)O^(-)Na^(+)` is a strong BASE, therefore, heating isopropyl BROMIDE with `C_(2)H_(5)O^(-)Na^(+)//C_(2)H_(5)OH` brings about dehydrohalogenation to yield propene.


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