1.

Amongst the various ores of a metal (M) (sulphide, carbonates, oxides, hydrated or hydrixides) two ores [X] and [Y] show the following reactivity? (a) [X[] on calcination gives a black solid (S), water and a colourless gas which produces milkiness when passed through lime water. But this colourless gas does not decolorise acidified KMnO_(4). (b) [X] dissolved in diliute HCl. On reaction with KI gives a white precipitate(P) and iodine gas. (c) [Y] on roasting at high temperature gives metal (M) and gas (G_(1)) which turns starch iodate solution blue. (d) [Y] on reaction with dilute HCl gives a white precipatate (MS) and another gas (G_(1)) to precipitate colloidal sulpher in presence of moisture. M,S[X],[Y] gives greenish blue flame. Which of the following statements is correct about [Y]?

Answer»

[Y] is converted to metal (M) by self reduction.
Carbon extract of [Y] gives YELLOW precipitate with suspension of `CdCO_(3)`.
[Y] is COPPER glance or copper pyrite.
All of the above

Solution :`"Colourless gas" to CO_(2)X to Cu^(2+), CO_(3)^(2-),OH^(-)`
G_(2) to H_(2)S, G_(1)to SO_(2),M to Cu, Sto CUO
Y to Cu^(2+), S^(2-)


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