1.

According to Born-Haber's cycle, the enthalpy of formation of ionic compounds can be determined. The formation of NaCl involves following steps – (i) Na(s)S−−−−−−−−−−−−−→Energy of subtimationNa(g) (ii) Na(g)I−−−−−−−−−−−→Ionisation potenitalNa+(g)+e− (iii) Cl2(g)D−−−−−−−−−−−−−−−→Bond dissociation energy2Cl(g) (iv) Cl(g)+e−E−−−−−−−−−−→Electron - affinityCl−(g) (v) Cl−(g)+Na+(g)U−−−−−−−−→Lattice energyNaCl(s) The enthalpy of formation of NaCl will be -

Answer»

According to Born-Haber's cycle, the enthalpy of formation of ionic compounds can be determined. The formation of NaCl involves following steps –
(i) Na(s)S−−−−−−−−−−−−Energy of subtimationNa(g)

(ii) Na(g)I−−−−−−−−−−Ionisation potenitalNa+(g)+e

(iii) Cl2(g)D−−−−−−−−−−−−−−Bond dissociation energy2Cl(g)

(iv) Cl(g)+eE−−−−−−−−−Electron - affinityCl(g)

(v) Cl(g)+Na+(g)U−−−−−−−Lattice energyNaCl(s)
The enthalpy of formation of NaCl will be -



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