1.

(a) Why does R3P = O exist but R3 N = O does not? (R = alkyl group)(b) Why is dioxygen a gas but sulphur a solid?(c) Why ate halogens coloured?

Answer»

(a) Due to absence of d- orbital,nitrogen cannot ex-pand its valency beyond there.

(b) Because of pπ- pπ multiple bonding in dioxy-gen which is absent in sulphur.Due to small size and high elctrogegativity oxygen acts as diatomic molecular held by weak van der waals' forces S Because of big siz and lower electonegativity form S-S single bonds.

(c) Due to excitation of electron by absorption  of rediation from visible region.



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