1.

A mixture of 1.57 mol of N_2 1.92 mol of H_2 and 8.13 mol of NH_3 is introduced into a 20 L reaction vessel at 500 K . At this temperature, the equilibrium constant K_c for the reactin. N_(2)(g)+3H_(2) (g)j hArr 2NH_(3)(g) is 1.7 xx 10^(-2) Is this reaction at equilibriuim ? if not , what is the direction of net rection ?

Answer»

SOLUTION :The reaction is `N_(2)(g) + 3H_(2)(g) hArr 2NH_(3)(g)`
Conecentration quotient `(Q_c)= ([NH_3]^)/([N_2][H_2]^3)`
`=((8.13/20 " mol "L^(-1))^1)/((1.57/20 "mol " L^(-1))xx(1.92/20 " mol "L^(-1))^3)=2.38 xx 10^3`
The equilibrium contant `(K_c)` for the reaction `=1.7 xx 10^(-2)`
As `Q_(C) NE K_(C)` , this means that the reaction is not in a state of equilibrium.


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