A chemist opened a cupboard to find four bottles containing water solutions, each of twhich had lost its lable. Bottles 1,2,3 contained colourless solutions , while bottle 4 contained coloured solution. They were, Copper (II) sulphate, Hydrochloric acid. Lead nitrate, Sodium carbonate. By mixing samples of the contents of the bottles, in pairs. The chemist made the following observations, Bottle `1+` Bottle 2 white precipitate Bottle `1=` Bottle 3 white precipitate Bottle `1+` Bottle 4 white precipitate Bottle `2+` Bottle 3 colour less gas evolved Bottle `2+` Bottle 4 no visible reaction Bottle `3+` Bottle 4 blue precipitate. Which of the bottle will give distinctive blue colour with `NH_(3)` ?A. Bottle 1B. Bottle 2C. Bottle 3D. Bottle 4

A chemist opened a cupboard to find four bottles containing water solu

1.	A chemist opened a cupboard to find four bottles containing water solutions, each of twhich had lost its lable. Bottles 1,2,3 contained colourless solutions , while bottle 4 contained coloured solution. They were, Copper (II) sulphate, Hydrochloric acid. Lead nitrate, Sodium carbonate. By mixing samples of the contents of the bottles, in pairs. The chemist made the following observations, Bottle `1+` Bottle 2 white precipitate Bottle `1=` Bottle 3 white precipitate Bottle `1+` Bottle 4 white precipitate Bottle `2+` Bottle 3 colour less gas evolved Bottle `2+` Bottle 4 no visible reaction Bottle `3+` Bottle 4 blue precipitate. Which of the bottle will give distinctive blue colour with `NH_(3)` ?A. Bottle 1B. Bottle 2C. Bottle 3D. Bottle 4
Answer» Correct Answer - 4 `CuSO_(4)+4Nh_(3)rarr[Cu(NH_(3))_(4)]SO_(4)`

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When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns light blue. Addition of aqueous `NaCl` to the blue solution gives a white precipitate O. Addition of aqueous `NH_(3)` dissolves O and gives an intense blue solution. The final solution containsA. `[Pb(NH_(3))_(4)]^(2+)` and `[CoCl_(4)]^(2-)`B. `[Al(NH_(3))_(4)]^(3+)]` and `[Cu(NH_(3))_(4)]^(2+)`C. `[Ag(NH_(3))_(2)]^(+)` and `[Cu(NH_(3))_(4)]^(2+)`D. `[Ag(NH_(3))_(2)]^(+)` and `[Ni(NH_(3))_(6)]^(2+)`
`(NH_(4))_(2)Cr_(2)O_(7)` on heating gives a gas which is also given byA. Heating `NH_(4)NO_(2)`B. Heating `NH_(4)NO_(3)`C. `Mg_(3)N_(2)+H_(2)O`D. `Na(comp.)+H_(2)O`
A sodium salt on treatment with `MgCl_(2)` gives white precipitate only on heating. The anion of sodium salt isA. `HCO_(3)^(-)`B. `CO_(3)^(2-)`C. `NO_(3)^(-)`D. `SO_(4)^(2-)`
To a metal nitrate, when KI solution is added, a black precipitate is produced at first , on additing excess of KI, orange solution is produced. Identify the meatl ionA. `Hg^(2+)`B. `Bi^(3+)`C. `Cu^(2+)`D. `Pb^(2+)`
A metal nitrate reacts with `KI` to give a black precipitate which on addition of excess of `KI` convert into orange colour solution. The cation of metal nitrate isA. `Hg^(2+)`B. `Bi^(3+)`C. `Sn^(2+)`D. `Pb^(2+)`
A metal nitrate reacts with `KI` to give a black precipitate which on addition of excess of `Kl` is converted into orange colour solution.The cation of the metal nitrate is :A. `Hg^(2+)`B. `Bi^(3+)`C. `Pb^(2+)`D. `Cu^(+)`
Assertion : Change in colour of the acidic solution of breath is used as a test for drunken driver. Reason : Change in colour is due to complexation of alcohol with potassium dichromate.
`S_(1) :` Silver iodide is fairly soluble in hypo solution. `S_(2) :` Heavy metal chloride like `AgCl,HgCl_(2)` etc. also respond to Chromyl chloride test. `S_(3) :` Bromine reacts with `KI` liberating violet vapours of iodine. `S_(4) :` Diphenylamine reagent test is also given by nitrites chlorates, bromates, iodates, etc. in addition to `NO_(3)^(-)`A. `T T T F`B. `T F T T`C. `T T F F `D. `F F T T `
Statement I Sulphate is extimated as `BaSO_(4)`, not as `MgSO_(4)`. Statement II Ionic radius of `Mg^(2+)` is smaller than that of `Ba^(2+)`.
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