A basic, volatile nitrogen compound gave a foul-smelling gas when treated withchloroform and alcoholic potash. A 0.295-g sample of the substance dissolved in aq. HC1 and treated with NaNO, solution at 0°C, liberated a colourless, colourless gas whose volume corresponded to 112 inL at STP. After the evolution of the gas was complete, the aqueous solution was distilled to give an organic liquid which did not contain nitrogen, and which on warming with an alkali and iodine, gave a yellow precipitate. Identify the original substance. Assume that it contains one N atom per molecule.

A basic, volatile nitrogen compound gave a foul-smelling gas when trea

1.	A basic, volatile nitrogen compound gave a foul-smelling gas when treated withchloroform and alcoholic potash. A 0.295-g sample of the substance dissolved in aq. HC1 and treated with NaNO, solution at 0°C, liberated a colourless, colourless gas whose volume corresponded to 112 inL at STP. After the evolution of the gas was complete, the aqueous solution was distilled to give an organic liquid which did not contain nitrogen, and which on warming with an alkali and iodine, gave a yellow precipitate. Identify the original substance. Assume that it contains one N atom per molecule.
Answer» SOLUTION :`(CH_3)_2 CHNH_2` (ISOPROPYLAMINE )