1.

(a) Account for the following : (i) o-nitrophenol is more steam volatile than p-nitrophenol. (ii) t-butyl chloride on heating with sodium methoxide gives 2-methylpropene instead of tbutylmethylether. (b) Write the reaction involved in the following : (i) Reimer-Tiemann reaction (ii) Friedal-Crafts Alkylation of Phenol (c) Give simple chemical test to distinguish between Ethanol and Phenol

Answer» (a) Account for the following :
(i) o-nitrophenol is more steam volatile than p-nitrophenol.
(ii) t-butyl chloride on heating with sodium methoxide gives 2-methylpropene instead of tbutylmethylether.
(b) Write the reaction involved in the following :
(i) Reimer-Tiemann reaction
(ii) Friedal-Crafts Alkylation of Phenol
(c) Give simple chemical test to distinguish between Ethanol and Phenol


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