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8. \( 5.5 g \) of sodium hydroxide is dissolved in \( 175 mL \) of water. Using a coffee-cup calorimeter, the temperature change of the water is measured to be \( +2.10^{\circ} C \). The specific heat capacity of water is \( 4.184 J / g ^{\circ} C \). What is the thermochemical equation for this process? (A) \( NaOH (s) \rightarrow NaOH ( aq )+1.54 kJ \) (B) \( NaOH ( s )+1.54 kJ \rightarrow NaOH ( aq ) \) (C) \( NaOH (s) \rightarrow NaOH ( aq )+11.2 kJ \) (D) \( NaOH ( s )+11.2 kJ \rightarrow NaOH ( aq ) \) |
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Answer» We have given----- Mass of NaOH = 5.5 g Volume of water = 175 ml Temperature change of water = +2.10°C specific Heat capacity of water = 4.184 J/g°C \(\because\) Temperature of water increases, it means, dissolution of NaOH in water is a exothormic process. We know that, density of water = 1 g/ml at STP \(\therefore\) Mass of water = 175 ml x 1g/mL = 175 g Heat absorbed by water Q = m x s x Δt where, m = mass of water S = specific Heat of water = 4.18 J/g°C Δt = change in temperature \(\therefore\) Q = 175 g x 4.18 4J/g°C x 2.10°C = 1.537 KJ = 1.54 KJ \(\therefore\) The correct Thermochemical equation will be---- NaOH(s) → NaOH(aq) + 1.54 KJ Hence, Option (A) is right answer. |
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