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48. A sequence of reactions is shown below starting from an optically active compound P. P does not react with 2,4-dinitrophenylhydrazine (2,4-DNP) to form a hydrazone. Q reacts very rapidly with one molar equivalent of ethylamine at low temperature to form R. Select the most appropriate statement(s). (A) Q as well as R are optically active. (B) Q on heating with an excess of ethylamine in the presence of a base gives a basic compound. (C) R is a basic compound and can react with an acid to form a salt. (D) An optically inactive isomer of P on heating can form compound S (C4H6O2) which does not react with thionyl chloride. |
| Answer» 48. A sequence of reactions is shown below starting from an optically active compound P. P does not react with 2,4-dinitrophenylhydrazine (2,4-DNP) to form a hydrazone. Q reacts very rapidly with one molar equivalent of ethylamine at low temperature to form R. Select the most appropriate statement(s). (A) Q as well as R are optically active. (B) Q on heating with an excess of ethylamine in the presence of a base gives a basic compound. (C) R is a basic compound and can react with an acid to form a salt. (D) An optically inactive isomer of P on heating can form compound S (C4H6O2) which does not react with thionyl chloride. | |