1.

20 gm of sample Ba(OH)_(2) is dissolved in 10 ml of 0.5 N HCl solution, The excess of HCl was titrated with 0.2 NaOH. The volume of NaOh used was 10 mol. Calculate the % of Ba(OH)_(2) in the sample.

Answer»

`1.5%`
`2.6%`
`3.4%`
`1.3%`

Solution :MILLI eq. of HCl initially = `10xx0.5=5`
Milli eq of NaOH consumed
= milli eq. of HCl in EXCESS = `10xx0.2-2`
`THEREFORE` m.eq of HCl consumed
= milli eq of `Ba(OH)_(2)=5-2=3`
Thus, equire of `Ba(OH)_(2)=3XX10^(-3)`
Mass of `Ba(OH)_(2)` = Equivalents `xx` Eq. wt
`=3xx10^(-3)xx(171//2)`
`=0.2565gm`
`therefore % Ba(OH)_(2)=(0.2565)/(20)xx100=1.28%`


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