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11 moles N2 and 12 moles of H2 mixture reacted in 20 L vessel at 800 K. After equilibrium was reached, 6 mole of H2 was present. 3.58 L of liquid water is injected in equilibrium mixture and resultant gaseous mixture suddenly cooled to 300 K. What is the final pressure of gaseous mixture/? Neglect vapour pressure of liquid solution. Assume (i) all NH3 dissolved in water (ii) no change in volume of liquid (iii) no reaction of N2 and H2 at 300 K (Given R=0.821 L atm mol−1 K−1)

Answer» 11 moles N2 and 12 moles of H2 mixture reacted in 20 L vessel at 800 K. After equilibrium was reached, 6 mole of H2 was present. 3.58 L of liquid water is injected in equilibrium mixture and resultant gaseous mixture suddenly cooled to 300 K. What is the final pressure of gaseous mixture/? Neglect vapour pressure of liquid solution. Assume (i) all NH3 dissolved in water (ii) no change in volume of liquid (iii) no reaction of N2 and H2 at 300 K

(Given R=0.821 L atm mol1 K1)


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